Intramolecular Pauson-Khand Reaction of 3-Alkynyl-1-Alkylideneclycles: A Convenient Synthesis of [5.n.1.01,5] Tricyclic Compounds
単著・共著の別
共著
著者
 
担当区分
 
概要
An intramolecular Pauson-Khand reaction of various 3-alkynyl-1- alkylidenecyclic compounds was performed to give the corresponding [5.n.1.01,5] tricyclic compounds (n = 2-4). A facile construction of the core structure in cedrene terpenoids was also investigated in detail and formal total synthesis of α- and β-cedrenes was accomplished. pp.827-844