Conference
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Basic information
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| Name | Ishizaki Miyuki |
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FACILE SYNTHESIS OF [5.n.1.01,5] TRICYCLES MEDIATED BY INTRAMOLECULAR PAUSON-KHAND REACTION: A FORMAL TOTAL SYNTHESIS OF CEDRENE TERPENOIDS
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24th International Symposium on the Chemistry of Natural Products and the 4th International Congress on Biodiversity New Delhi (India)
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2004/01/30
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Url
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In our continuing studies on Pauson-Khand reaction (PKR) of exo-cyclic enynes,1 we examined synthesis of [5.n.1.01,5] tricyclic compounds (n = 2-4) by intramolecular PKR of various 3-alkynyl-1-alkylidenecyclic compounds. We applied the present reaction to formal total synthesis of α- and β-cedrenes.
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