Academic Thesis
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Basic information
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| Name | Nakamura Hiroshi |
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A novel feature in phenyliodine diacetate oxidation
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Joint Author
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Phenyliodine diacetae (PIDA) oxidn. of N-benzyl-N-(benzyloxycarbonyl)tyrosine followed by quenching with aq. sodium chloride or bromide soln. gave the corresponding dihalocyclohexadienone lactones I [R = Cl, Br; R1 = N(CH2Ph)CO2CH2Ph]. With p-hydroxydihydrocinnamic acid similar PIDA oxidn. was obsd. to give I (R = Cl, Br; R1 = H). A plausible mechanism for the reaction is also described.
(1992), 33(43), 6491-4
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Tetrahedron Letters
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1992/11
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